已知\(\rm{H^{+}(aq)+OH^{-}(aq)═H_{2}O(l)\triangle H=-57.3kJ⋅mol^{-1}.}\)以下四个化学方程式其中反应热为\(\rm{-57.3kJ⋅mol^{-1}}\)的是\(\rm{(}\)　　\(\rm{)}\)
\(\rm{①H_{2}SO_{4}(aq)+2NaOH(aq)═Na_{2}SO_{4}(aq)+2H_{2}O(l)}\)
\(\rm{②H_{2}SO_{4}(aq)+Ba(OH)_{2}(aq)═BaSO_{4}(s)+2H_{2}O(l)}\)
\(\rm{③HCl(aq)+NH_{3}⋅H_{2}O(aq)═NH_{4}Cl(aq)+H_{2}O(l)}\)
\(\rm{④CH_{3}COOH(aq)+NH_{3}⋅H_{2}O(aq)═CH_{3}COONH_{4}(aq)+H_{2}O(l)}\)

A．\(\rm{①}\)和\(\rm{②}\)

B．\(\rm{③}\)

C．\(\rm{④}\)

D．以上都不对

【考点】中和热

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