写出下列反应的热化学方程式． \(m{⑴16}\) \(m{g}\)\(m{CH_{4}(}\)\(m{g}\)\(m{)}\)与适量\(m{O_{2}(}\)\(m{g}\)\(m{)}\)反应生成\(m{CO_{2}(}\)\(m{g}\)\(m{)}\)和\(m{H_{2}O(}\)\(m{l}\)\(m{)}\)，放出\(m{890.3}\)\(m{k}\)\(m{J}\)热量______ \(m{⑵}\)在\(m{101}\)\(m{k}\)\(m{P}\)\(m{a}\)时，\(m{H_{2}}\)在\(m{1}\)\(m{mol}\)\(m{O_{2}}\)中完全燃烧生成\(m{2}\)\(m{mol}\)液态水，放出\(m{571.6}\)\(m{k}\)\(m{J}\)的热量，写出\(m{H_{2}}\)燃烧热的热化学方程式为______ \(m{⑶1.00L}\)\(m{1.00}\)\(m{mol}\)\(m{/L}\)硫酸与\(m{2.00L}\)\(m{1.00}\)\(m{mol}\)\(m{/L}\)\(m{N}\)\(m{a}\)\(m{OH}\)溶液完全反应，放出\(m{114.6}\)\(m{k}\)\(m{J}\)的热量，表示其中和热的热化学方程式为______ \(m{(4)}\)已知拆开\(m{1}\)\(m{mol}\)\(m{H-H}\)键，\(m{1}\)\(m{mol}\)\(m{N-H}\)键，\(m{1}\)\(m{mol}\)\(m{N≡N}\)键分别需要的能量是\(m{436}\)\(m{k}\)J、\(m{391}\)\(m{k}\)J、\(m{946}\)\(m{k}\)\(m{J}\)，则\(m{N_{2}(}\)\(m{g}\)\(m{)}\)与\(m{H_{2}(}\)\(m{g}\)\(m{)}\)反应生成\(m{NH_{3}(}\)\(m{g}\)\(m{)}\)的热化学方程式为______ \(m{(5)}\)已知：\(m{①F}\)\(m{e}\)\(m{{\,\!}_{2}O_{3}(}\)\(m{s}\)\(m{)+3CO(}\)\(m{g}\)\(m{)═2F}\)\(m{e}\)\(m{(}\)\(m{s}\)\(m{)+3CO_{2}(}\)\(m{g}\)\(m{)\triangle H_{1}=-25}\)\(m{k}\)\(m{J/}\)\(m{mol}\) \(m{②3F}\)\(m{e}\)\(m{{\,\!}_{2}O_{3}(}\)\(m{s}\)\(m{)+CO(}\)\(m{g}\)\(m{)═2F}\)\(m{e}\)\(m{{\,\!}_{3}O_{4}(}\)\(m{s}\)\(m{)+CO_{2}(}\)\(m{g}\)\(m{)\triangle H_{2}=-47}\)\(m{k}\)\(m{J/}\)\(m{mol}\) \(m{③F}\)\(m{e}\)\(m{{\,\!}_{3}O_{4}(}\)\(m{s}\)\(m{)+CO(}\)\(m{g}\)\(m{)═3F}\)\(m{e}\)\(m{O(}\)\(m{s}\)\(m{)+CO_{2}(}\)\(m{g}\)\(m{)\triangle H_{3}=+19}\)\(m{k}\)\(m{J/}\)\(m{mol}\) 请写出\(m{CO}\)还原\(m{F}\)\(m{e}\)\(m{O}\)的热化学方程式：______ \(m{(6)}\)在\(m{101}\)\(m{k}\)\(m{P}\)\(m{a}\)下，\(m{CH_{4}(}\)\(m{g}\)\(m{)}\)、\(m{H_{2}(}\)\(m{g}\)\(m{)}\)、\(m{C(}\)\(m{s}\)\(m{)}\)的燃烧热分别为\(m{890.3}\)\(m{k}\)\(m{J/}\)\(m{mol}\)、\(m{285.8}\)\(m{k}\)\(m{J/}\)\(m{mol}\)和\(m{393.5}\)\(m{k}\)\(m{J/}\)\(m{mol}\)，则\(m{CH_{4}(}\)\(m{g}\)\(m{)}\)分解为\(m{H_{2}(}\)\(m{g}\)\(m{)}\)、\(m{C(}\)\(m{s}\)\(m{)}\)的热化学方程式_____

写出下列反应的热化学方程式．

\(\rm{⑴16}\) \(\rm{g}\) \(\rm{CH_{4}(}\)\(\rm{g}\)\(\rm{)}\)与适量\(\rm{O_{2}(}\)\(\rm{g}\)\(\rm{)}\)反应生成\(\rm{CO_{2}(}\)\(\rm{g}\)\(\rm{)}\)和\(\rm{H_{2}O(}\)\(\rm{l}\)\(\rm{)}\)，放出\(\rm{890.3}\)\(\rm{k}\)\(\rm{J}\)热量______

\(\rm{⑵}\)在\(\rm{101}\)\(\rm{k}\)\(\rm{P}\)\(\rm{a}\)时，\(\rm{H_{2}}\)在\(\rm{1}\)\(\rm{mol}\) \(\rm{O_{2}}\)中完全燃烧生成\(\rm{2}\)\(\rm{mol}\)液态水，放出\(\rm{571.6}\)\(\rm{k}\)\(\rm{J}\)的热量，写出\(\rm{H_{2}}\)燃烧热的热化学方程式为______

\(\rm{⑶1.00L}\) \(\rm{1.00}\)\(\rm{mol}\)\(\rm{/L}\)硫酸与\(\rm{2.00L}\) \(\rm{1.00}\)\(\rm{mol}\)\(\rm{/L}\) \(\rm{N}\)\(\rm{a}\)\(\rm{OH}\)溶液完全反应，放出\(\rm{114.6}\)\(\rm{k}\)\(\rm{J}\)的热量，表示其中和热的热化学方程式为______

\(\rm{(4)}\)已知拆开\(\rm{1}\)\(\rm{mol}\) \(\rm{H-H}\)键，\(\rm{1}\)\(\rm{mol}\) \(\rm{N-H}\)键，\(\rm{1}\)\(\rm{mol}\) \(\rm{N≡N}\)键分别需要的能量是\(\rm{436}\)\(\rm{k}\)J、\(\rm{391}\)\(\rm{k}\)J、\(\rm{946}\)\(\rm{k}\)\(\rm{J}\)，则\(\rm{N_{2}(}\)\(\rm{g}\)\(\rm{)}\)与\(\rm{H_{2}(}\)\(\rm{g}\)\(\rm{)}\)反应生成\(\rm{NH_{3}(}\)\(\rm{g}\)\(\rm{)}\)的热化学方程式为______

\(\rm{(5)}\)已知：\(\rm{①F}\)\(\rm{e}\)\(\rm{{\,\!}_{2}O_{3}(}\)\(\rm{s}\)\(\rm{)+3CO(}\)\(\rm{g}\)\(\rm{)═2F}\)\(\rm{e}\)\(\rm{(}\)\(\rm{s}\)\(\rm{)+3CO_{2}(}\)\(\rm{g}\)\(\rm{)\triangle H_{1}=-25}\)\(\rm{k}\)\(\rm{J/}\)\(\rm{mol}\)

\(\rm{②3F}\)\(\rm{e}\)\(\rm{{\,\!}_{2}O_{3}(}\)\(\rm{s}\)\(\rm{)+CO(}\)\(\rm{g}\)\(\rm{)═2F}\)\(\rm{e}\)\(\rm{{\,\!}_{3}O_{4}(}\)\(\rm{s}\)\(\rm{)+CO_{2}(}\)\(\rm{g}\)\(\rm{)\triangle H_{2}=-47}\)\(\rm{k}\)\(\rm{J/}\)\(\rm{mol}\)

\(\rm{③F}\)\(\rm{e}\)\(\rm{{\,\!}_{3}O_{4}(}\)\(\rm{s}\)\(\rm{)+CO(}\)\(\rm{g}\)\(\rm{)═3F}\)\(\rm{e}\)\(\rm{O(}\)\(\rm{s}\)\(\rm{)+CO_{2}(}\)\(\rm{g}\)\(\rm{)\triangle H_{3}=+19}\)\(\rm{k}\)\(\rm{J/}\)\(\rm{mol}\)

请写出\(\rm{CO}\)还原\(\rm{F}\)\(\rm{e}\)\(\rm{O}\)的热化学方程式：______

\(\rm{(6)}\)在\(\rm{101}\)\(\rm{k}\)\(\rm{P}\)\(\rm{a}\)下，\(\rm{CH_{4}(}\)\(\rm{g}\)\(\rm{)}\)、\(\rm{H_{2}(}\)\(\rm{g}\)\(\rm{)}\)、\(\rm{C(}\)\(\rm{s}\)\(\rm{)}\)的燃烧热分别为\(\rm{890.3}\)\(\rm{k}\)\(\rm{J/}\)\(\rm{mol}\)、\(\rm{285.8}\)\(\rm{k}\)\(\rm{J/}\)\(\rm{mol}\)和\(\rm{393.5}\)\(\rm{k}\)\(\rm{J/}\)\(\rm{mol}\)，则\(\rm{CH_{4}(}\)\(\rm{g}\)\(\rm{)}\)分解为\(\rm{H_{2}(}\)\(\rm{g}\)\(\rm{)}\)、\(\rm{C(}\)\(\rm{s}\)\(\rm{)}\)的热化学方程式______．

【考点】热化学方程式,中和热,燃烧热,用盖斯定律及有关计算

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难度：难

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