温度为\(\rm{T_{1}}\)时,在三个容积均为\(\rm{1L}\)的恒容密闭容器中仅发生反应:\(\rm{2NO_{2}(g)⇌2NO(g)+O_{2}(g)(}\)正反应吸热\(\rm{).}\)实验测得:\(\rm{v_{正}=v}\) \(\rm{(NO_{2}}\) \(\rm{)_{消耗}=k_{正}c^{2}(NO_{2}}\) \(\rm{)}\),\(\rm{v_{逆}=v(NO)_{消耗}=2v}\) \(\rm{(O_{2}}\) \(\rm{)_{消耗}=k_{逆}c^{2}}\) \(\rm{(NO)⋅c(O_{2}}\) \(\rm{)}\),\(\rm{k_{正}}\)、\(\rm{k_{逆}}\)为速率常数,受温度影响\(\rm{.}\)下列说法正确的是\(\rm{(}\) \(\rm{)}\)
容器编号 | 物质的起始浓度\(\rm{(mol⋅L^{-1})}\) | 物质的平衡浓度\(\rm{(mol⋅L^{-1})}\) |
\(\rm{c(NO_{2})}\) | \(\rm{c(NO)}\) | \(\rm{c(O_{2})}\) | \(\rm{c(O_{2})}\) |
Ⅰ | \(\rm{0.6}\) | \(\rm{0}\) | \(\rm{0}\) | \(\rm{0.2}\) |
Ⅱ | \(\rm{0.3}\) | \(\rm{0.5}\) | \(\rm{0.2}\) |
|
Ⅲ | \(\rm{0}\) | \(\rm{0.5}\) | \(\rm{0.35}\) |
|